Thermal and Rheological Properties Improvement of Oil-based Drilling Fluids Using Multi-walled Carbon Nanotubes (MWCNT)

Document Type : Research Paper

Authors

1 Researcher at National Iranian Drilling Company

2 Assistant Professor at University of Tehran

3 Assistant Professor at Petroleum University of Technology (Iran)

Abstract

In this paper, we detail our results for the impact of MWCNT on the thermal and rheological properties of oil-based drilling muds. Our analysis considers the effects of time, temperature, and MWCNT volume fraction. The scanning electron microscopy imaging technique was used to monitor the MWCNTsdispersion quality. The experimental results unveil a considerable enhancement in the thermal conductivity of the MWCNT-oil-based mud by 40.3% (and 43.1% in case of functionalized MWCNT) and 1% vol. MWCNT. The rheological properties results for the MWCNT-oil-based mud exhibit a similar (improvement) trend by reducing annular viscosity and increasing yield point and gel strength. The high-temperature high-pressure filtration tests conducted at 280°F and 500 psi show a  reduction of 16.67% for the filtrate amount in case of MWCNT-oil-based mud (with 1% vol. MWCNT). The effect of time on thermal conductivity reduction in both unfunctionalized and functionalized systems was observed to equalize (at 9.7%), after 100 hours of sample preparation. The performance results of MWCNT-oil-based mud are presented for an actual industrial drilling operation case.

Keywords


        [1]            Aladag B., Halelfadl S., Donera N., Maré T., et al., “Experimental Investigations of The Viscosity of Nanofluids at Low Temperatures,” Applied Energy, 2012, 97, 876-880.
      [2]     Chen L., Xie H., Yu W., and Li Y. “Rheological Behaviors of Nanofluids Containing Multi-Walled Carbon Nanotube,” Journal of Dispersion Science and Technology, 2011, 32, 550-554.
            [3]            Hobbie E. K. and Fry D. J., “Rheology of Concentrated Carbon Nanotube Suspensions” Journal of Chemical Physics,2007, 126, 124907-124914.
            [4]            Jyothirmayee Aravind S. S., Baskar P., Baby T. T., Sabareesh R. K., et al., “Investigation of Structural Stability, Dispersion, Viscosity, and Conductive Heat Transfer Properties of Functionalized Carbon Nanotube Based Nanofluids,” Journal of Physical Chemistry C., 2011, 115, 16737-16744.
            [5]            Lei Y., Xiong C., Guo H., Yao J., et al., “Controlled Viscoelastic Carbon Nanotube Fluids,” Journal of American Chemical Society, 2008, 130, 3256-3257.
            [6]            Murshed S. M. S., Leong K. C., and Yang C. “Investigations of Thermal Conductivity and Viscosity of Nanofluids,” International Journal of Thermal Science, 2008, 47, 560-568.
            [7]            Phuoc T., Massoudi M., and Chen R., “Viscosity and Thermal Conductivity of Nanofluids Containing Multi-walled Carbon Nanotubes Stabilized by Chitosan,” International Journal of Thermal Science, 2011, 50, 12-18.
      [8]     Vakili-Nezhaad G. R. and Dorany A., “Investigation of the Effect of Multi-walled Carbon Nanotubes on the Viscosity Index of Lube Oil Cuts,” Chemical Engineering Communication, 2009, 196, 997-1007.
            [9]            Ding Y., Alias H., Wen D., and Williams R. A., “Heat Transfer of Aqueous Suspensions of Carbon Nanotubes (CNT Nanofluids),” International Journal of Heat and Mass Transfer, 2006, 49, 240-250.
         [10]         Hwang Y. J., Ahn Y. C., Shin H. S., Lee C. G., et al., “Investigation on Characteristics of Thermal Conductivity Enhancement of Nanofluids,” Current Applied Physics, 2006, 6, 1068-1071.
    [11]    Kalinina I., Worsley K., Lugo C., Mandal S., et al., “Synthesis, Dispersion, and Viscosity of Poly(ethylene glycol)-Functionalized Water-Soluble Single-Walled Carbon Nanotubes,” Chemistry of Materials, 2011, 23, 1246-1253.
    [12]    Kleinstreuer C. and Feng Y., “Experimental and Theoretical Studies of Nanofluid Thermal Conductivity Enhancement: a review,” Nanoscale Research Letters, 2011, 6, 229-242.
    [13]    Liu M. S., Lin M. C., Huong I. T., and Wang C. C., “Enhancement of Thermal Conductivity with Carbon Nanotube for Nanofluids,” International Communications in Heat and Mass Transfer, 2005, 32, 1202-1210.
         [14]         Özerinç S., Kakaç S., and Yazıcıoğlu A. G., “Enhanced Thermal Conductivity of Nanofluids: a State-of-the-art Review,” Microfluidics and Nanofluidics, 2010, 8, 145-170.
         [15]         Venkata Sastry N. N., Bhunia A., Sundararajan T., and Das S. K., “Predicting the Effective Thermal Conductivity of Carbon Nanotube Based Nanofluids,” Nanotechnology, 2008, 19, 055704.
    [16]    Xie H. and Chen L. “Adjustable Thermal Conductivity in Carbon Nanotube Nanofluids,” Physics Letters A, 2009, 21, 1861-1864.