Experimental study on viscosity reduction of Iranian heavy export crude oil by using imidazolium based ionic liquids supported on ZIF-8 organic framework
Chemical - Thermal Technology is used to upgrade the quality and to decrease the viscosity of Iranian extra-heavy crude oil in atmospheric pressure. In this present study, quality preparation of [OMIM][NTf2]-ZIF-8 (IL@ZIF-8) nanostructures were performed solvothermal by using an oil-soluble long chain Ionic Liquids, [OMIM][NTf2] and a zeolitic imidazolate framework, ZIF-8. This complex was used in the thermal cracking of heavy oil as a chemical additive. The injection of a small amount of the IL@ZIF-8 into extra-heavy oil caused the production of gaseous compounds, naphtha, middle distillates, lubricating oil, and tar. The viscosity measurement results show an evident viscosity reduction of 91% for extra-heavy oil after chemical-thermal cracking at 370 °C for a maximum of 120 min. The technique is ideally suited for cracking extra-heavy Iranian Crude oils, such as in the Nowrooz-Soroosh oilfields. To our knowledge, no report has been found about the chemothermal cracking of heavy crude oils, especially by using IL@ZIF-8 metal-organic frameworks.
Zhao, F., Liu, Y., Lu, N., Xu, T., Zhu, G., & Wang, K. (2021). A review on upgrading and viscosity reduction of heavy oil and bitumen by underground catalytic cracking, Energy Reports, 7, 4249-4272,. doi.org/10.1016/j.egyr.2021.06.094. ##
Li, Y., Wang, Z., Hu, Z., Xu, B., Li, Y., Pu, W., & Zhao, J. (2021). A review of in situ upgrading technology for heavy crude oil. Petroleum, 7(2), 117-122, doi.org/10.1016/j.petlm.2020.09.004. ##
Morelos Santos, O., Reyes, de la Torre, A. I., Schacht-Hernandez, P., Portales-Martinez, B., Soto-Escalante, I., Mendoza-Martinez, A. M., Mendoza-Cruz, R., Velazquez-Salazar, J. J., Jose-Yacaman, M. (2019). NiFe2O4 nanocatalyst for heavy crude oil upgrading in low hydrogen/feedstock ratio, Catalyst Today, 12517. doi.org/10.1016/j.cattod.2019.10.012. ##
Hanyong, L., Kexin, C., Ling, J., Leilei, W. & Bo, Y. (2018). Experimental study on the viscosity reduction of heavy oil with nanocatalyst by microwave heating under low reaction temperature, Journal of Petroleum Science and Engineering, 177, 374-382, doi.org/10.1016/j.petrol.2018.06.078. ##
Chunhao, W., Ruihe, W., Weidong, Z. & Luopeng, L. (2019). Experimental study on viscosity reduction of heavy oil by hydrogen donors using a cavitating jet, RSC Avances, 9, 2509, 9, 2509-2515 doi:10.1039/C8RA08087A (Paper) RSC Adv. ##
Wang, W., Cui, J., Wu, S., Cheng, Y., Wang, G., & Zhang, H. (2019). Isolation and optimization of compound bacteria for wax content and particle size, Journal of Petroleum Science and Technology, 9(4), 53-62, doi:10.22078/JPST.2019.3499.1563. ##
Chen, G., Zhou, Z., Shi, X., Zhang, X., Dong, S., & Zhang, J. (2021). Synthesis of alkylbenzenesulfonate and its behavior as flow improver in crude oil, Fuel, 288, 119644, doi.org/10.1016/j.fuel.2020.119644. ##
Chen, Q., Shan, Y., Liu, H., Zhao, B., & Cao, J. (2020). Upgrading of Venezuela extra-heavy oil vacuum residue by two-step thermal treatment. Petroleum Science and Technology, 38(3), 166-169, doi.org/10.1080/10916466.2019.1697285. ##
Taghili, N., Manteghian, M., & Jafari, A. (2020). Novel preparation of MoO3/γ-Al2O3 nanocatalyst: application in extra-heavy oil visbreaking at atmospheric pressure, Applied Nanoscience, 10(5), 1603-1613, doi.org/10.1007/s13204-020-01271-8. ##
Razavian, M., & Fatemi, S. (2021). Catalytic evaluation of metal azolate framework-6 in pristine and metal doped modes in upgrading heavy residual fuel oil, Journal of Analytical and Applied Pyrolysis, 156, 105093, doi.org/10.1016/j.jaap.2021.105093. ##
Głowniak, S., Szczęśniak, B., Choma, J., & Jaroniec, M. (2021). Mechanochemistry: Toward green synthesis of metal–organic frameworks, Materials Today, 46, 109-124, doi.org/10.1016/j.mattod.2021.01.008. ##
Shet, S. P., Priya, S. S., Sudhakar, K., & Tahir, M. (2021). A review on current trends in potential use of metal-organic framework for hydrogen storage, International Journal of Hydrogen Energy, 46(21), 11782-11803, doi.org/10.1016/j.ijhydene.2021.01.020. ##
Zhao, D. L., Feng, F., Shen, L., Huang, Z., Zhao, Q., Lin, H., & Chung, T. S. (2023). Engineering metal–organic frameworks (MOFs) based thin-film nanocomposite (TFN) membranes for molecular separation, Chemical Engineering Journal, 454, 140447, doi.org/10.1016/j.cej.2022.140447. ##
Jian, M., Liu, B., Liu, R., Qu, J., Wang, H., & Zhang, X. (2015). Water-based synthesis of zeolitic imidazolate framework-8 with high morphology level at room temperature. Rsc Advances, 5(60), 48433-48441, 5, 48433-48441, doi:10.1039/C5RA04033G (Paper) RSC Adv. ##
Zunita, M., Natola, W., David, M., & Lugito, G. (2022). Integrated metal organic framework/ionic liquid-based composite membrane for CO2 separation, Chemical Engineering Journal Advances, 11, 100320, doi.org/10.1016/j.ceja.2022.100320. ##
Nalesso, S., Varlet, G., Bussemaker, M. J., Sear, R. P., Hodnett, M., Monteagudo-Olivan, R., Sebastian, V., Coronas, J. & Lee, J. (2021). Sonocrystallisation of ZIF-8 in water with high excess of ligand: effects of frequency, power and sonication time, Ultrasonics Sonochemistry, 76,105616, doi.org/10.1016/j.ultsonch.2021.105616. ##
Liu, S., Liu, J., Hou, X., Xu, T., Tong, J., Zhang, J., Ye B. & Liu, B. (2018). Porous liquid: a stable ZIF-8 colloid in ionic liquid with permanent porosity. Langmuir, 34(12), 3654-3660, doi.org/10.1021/acs.langmuir.7b04212. ##
Mehdizadeh, A., Masoumi, F., Ahmadi, A. N., Shekarriz, M., & Ghamami, S. (2022). Enhancement of efficiency of water removal from bangestan crude oil by silica nanoparticles using imidazolium-based ionic liquids, Journal of Petroleum Science and Technology, 12(2), 51-58, doi:10.22078/JPST.2023.4855.1813. ##
Taheri, M., Bernardo, I. D., Lowe, A., Nisbet, D. R., & Tsuzuki, T. (2020). Green full conversion of ZnO nanopowders to well-dispersed zeolitic imidazolate framework-8 (ZIF-8) nanopowders via a stoichiometric mechanochemical reaction for fast dye adsorption. Crystal Growth & Design, 20(4), 2761-2773, doi.org/10.1021/acs.cgd.0c00129. ##
Shoja, S. M. R., Abdouss, M., Beigi, A. A. M., & Saeedirad, R. (2022). Synthesis and application of ionic liquid/ZIF-8 as a pH-sensitive nanocarrier for slow release of 1-(2- hydroxy ethyl)-3-methylimidazolium dicyanamide corrosion inhibitor in neutral chloride solution. Materials Today Communications, 33, 104829, doi.org/10.1016/j.mtcomm.2022.104829. ##
Hazrati, N., Abdouss, M., Miran Beigi, A. A., Pasban, A. A., & Rezaei, M. (2017). Physicochemical properties of long chain alkylated imidazolium based chloride and bis (trifluoromethanesulfonyl) imide ionic liquids, Journal of Chemical & Engineering Data, 62(10), 3084-3094, doi.org/10.1021/acs.jced.7b00242. ##
Zunita, M., Natola, W., David, M., & Lugito, G. (2022). Integrated metal organic framework/ionic liquid-based composite membrane for CO2 Chemical Engineering Journal Advances, 11, 100320, doi.org/10.1016/j.ceja.2022.100320. ##
Xiong, Y., Deng, N., Wu, X., Zhang, Q., Liu, S., & Sun, G. (2022). De novo synthesis of amino-functionalized ZIF-8 nanoparticles: Enhanced interfacial compatibility and pervaporation performance in mixed matrix membranes applying for ethanol dehydration. Separation and Purification Technology, 285, 120321, doi.org/10.1016/j.seppur.2021.120321. ##
Gray, M. R., Ayasse, A. R., Chan, E. W., & Veljkovic, M. (1995). Kinetics of hydrodesulfurization of thiophenic and sulfide sulfur in Athabasca bitumen, Energy & Fuels, 9(3), 500-506, doi.org/10.1021/ef00051a015. ##
Anand, M., Sibi, M. G., Verma, D., & Sinha, A. K. (2014). Anomalous hydrocracking of triglycerides over CoMo-catalyst–influence of reaction intermediates, Journal of Chemical Sciences, 126, 473-480, doi.org/10.1007/s12039-014-0587-y. ##
Pasban, A. A., Asghari, A., Miran Beigi, A., & Rajabi, M. (2023). Experimental study on viscosity reduction of Iranian heavy export crude oil by using imidazolium based ionic liquids supported on ZIF-8 organic framework. Journal of Petroleum Science and Technology, 13(3), 2-8. doi: 10.22078/jpst.2024.5102.1874
MLA
Ali Asghar Pasban; Ali Reza Asghari; Ali Akbar Miran Beigi; Maryam Rajabi. "Experimental study on viscosity reduction of Iranian heavy export crude oil by using imidazolium based ionic liquids supported on ZIF-8 organic framework". Journal of Petroleum Science and Technology, 13, 3, 2023, 2-8. doi: 10.22078/jpst.2024.5102.1874
HARVARD
Pasban, A. A., Asghari, A., Miran Beigi, A., Rajabi, M. (2023). 'Experimental study on viscosity reduction of Iranian heavy export crude oil by using imidazolium based ionic liquids supported on ZIF-8 organic framework', Journal of Petroleum Science and Technology, 13(3), pp. 2-8. doi: 10.22078/jpst.2024.5102.1874
VANCOUVER
Pasban, A. A., Asghari, A., Miran Beigi, A., Rajabi, M. Experimental study on viscosity reduction of Iranian heavy export crude oil by using imidazolium based ionic liquids supported on ZIF-8 organic framework. Journal of Petroleum Science and Technology, 2023; 13(3): 2-8. doi: 10.22078/jpst.2024.5102.1874